I should have been more clear; “those” should have been “the latter”, referring to the carbon compounds, not active metals. Yes, silica is a strong oxidizer relative to the group 1 and 2 metals. Carbonate in lime is a problem with lithium metal as I have been informed (Bretherick’s).
I thought that sand (SiO2) reacted with some metals. I remember an experiment where sand mixed with Mg shavings started an exothermic reaction that produced Si and MgO. The glass test tube glowed red and partially melted from the heat of the reaction. I would think that Li, Na, K, and Cs would be more aggressive toward sand than Mg.
I would think that this kind of reaction could make a metal fire situation worse, although the slag produced could potentially cut off oxygen from the metal.
The specialized class-D extinguisher materials are specifically for the burning active metals, especially lithium, which is the most reducing of them. The metal alkyls are quite different even though they react as readily with air as do metals. The metals in the case of alkyls are not as elemental, but as essentially ions, ie. inert. The carbon anion is very reactive with oxygen but releases about the same energy per oxygen atom as any ordinary organic compound. The active metals, as elements, produce much greater heat per oxygen atom (or mole of them) than carbon compounds. Smothering those with sand or lime should suffice. The alkylide ion reacts with hydrogen ion, water is a strong acid by comparison and thus vigorous, but it doesn’t become hydrogen in the process. A light alkylide will become a hydrocarbon vapor and ignite in air if auto-ignition temperature and limits of flammability happen to be co-incident.
Bretherick’s handbook has a very good summary on materials for extinguishing fires of the group 1 metals.
I am looking into the advantages and disadvantages of using Met-L-X or Lith-X scoopable dry powder extinguishing agent versus outfitting labs with the extremely large dry powder extinguishers that this material traditionally comes in. I am hoping for a solution for the usual pyrophoric and reactive metal suspects; alkyllithiums, trimethyl aluminum, diethyl zinc, potassium, sodium, magnesium, etc.
If anyone has an experience with using or training with this extinguishing, I would appreciate any insight that you might have. I have already contacted Ansul and am awaiting their response.
Brandon S. Chance, M.S., CCHO
Program Manager, Chemical Safety
Environmental Health and Safety
262 Alexander Street
Princeton, NJ 08540
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