From: Yaritza Brinker <YBrinker**At_Symbol_Here**FELE.COM>
Subject: Re: [DCHAS-L] Lead contamination [was: [DCHAS-L] Is lead sheeting a source of lead dust? And-Chemical Exposure question...
Date: Thu, 1 Aug 2019 18:22:48 +0000
Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU>
Message-ID: BL0PR05MB464115BBDC9B5ED8EEFF4AE0ADDE0**At_Symbol_Here**BL0PR05MB4641.namprd05.prod.outlook.com
In-Reply-To <8F68C5E4938BAF48AFF8372B510DB34101186C7D1E**At_Symbol_Here**WMC-EXCHANGE.whipmix.whipmix.corp>


For those of you interested on more about PbÉ

 

Title       Lead: Chemistry, Analytical Aspects, Environmental Impact and Health Effects

Editors  Jose´ S. Casas, Jose´ Sordo

Publisher              Elsevier, 2011

ISBN      0080463886, 9780080463889

 

Thank you,

 

Yaritza Brinker

260.827.5402

 

From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU> On Behalf Of Harold Ingmire
Sent: Thursday, August 1, 2019 12:08 PM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: Re: [DCHAS-L] Lead contamination [was: [DCHAS-L] Is lead sheeting a source of lead dust? And-Chemical Exposure question...

 

** External Email **

I would recommend caution in dealing with the issue of "pregnant women", as this became a huge issue with Johnson Controls, Inc. back in the early 1990's in their automotive battery plans (I was HR/Safety in one.) The case was based on discrimination against women as they were removed from "leaded" areas and/or denied opportunities in those areas. While this never officially went through OSHA, the  bigger issue you will have is ensuring you meet all the OSHA standards concerning the Lead Standard as for proper PPE, sanitation, clothing, footwear, etc., plus a proper medical surveillance program. Of course the best practices you can have to maintain the lowest exposure to lead is preferred.

 

From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU> On Behalf Of Monona Rossol
Sent: Thursday, August 01, 2019 7:03 AM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: Re: [DCHAS-L] Lead contamination [was: [DCHAS-L] Is lead sheeting a source of lead dust? And-Chemical Exposure question...

 

** CAUTION: This email originated from outside of the organization. Do not click links or open attachments unless you recognize the sender and know the content is safe. **

So very interesting, Stephen.  The only thing I would add would be to your comment #1.

1.  I would think that your workers exposure would be minimal, and 

I wouldn't leave it to my "thinking" alone.  Why not do a lead wipe in the area and quantify the potential for exposure?   OSHA cites at 200 ug/ft2 for housekeeping violations under the OSHA Lead Standard.  So it certainly should be under this.  And you might want to go a lot lower if there are women who may be pregnant in the area.  The old HUD residential standard is 40 and the new is 10 ug/ft2.

 

And if the wipe sample level is high, I would be testing to find out how far the lead has been tracked around.  I will not go into a long story here -- only I'll tell you that in one case where there was lead dust like this, many nearby departments had floors that also exceeded the standards.  Wouldn't it be ducky to just KNOW if there is a problem or not?

 

Monona

 

-----Original Message-----
From: Stephen Stepenuck <sstepenuck**At_Symbol_Here**NE.RR.COM>
To: DCHAS-L <DCHAS-L**At_Symbol_Here**PRINCETON.EDU>
Sent: Thu, Aug 1, 2019 5:52 am
Subject: Re: [DCHAS-L] Lead contamination [was: [DCHAS-L] Is lead sheeting a source of lead dust? And-Chemical Exposure question...

Monona, et al.,

The "Boston EPA" results almost certainly came from the EPA Region 1 lab in Bedford, and I'll bet were done by Dr. Tom Spittler.  I did a sabbatical with him in the 1990s, and learned a lot.  Some community agency planning a garden on some of its property had brought a soil sample to him for a "routine check."  He found astronomically high levels of Pb, and communicated his serious concerns re a garden there.   He went on to document excess lead in countless other places, but alas I don't have a specific reference to a publication.  Hopefully the name, and the affiliation as Jim said  will be helpful.  

One irony of all that work was that the safety officer at the site pointed out that of course, no part of any of the samples he had received over the yearsÑand there were drums of them by the time I arrivedÑcould be disposed of as trash since they were of course hazardous waste.  [We won't think about 90-day limits because of course they might be used for something. ..].  Then came NIST [National Institute of Standards and Technology] to the rescue: would he please send them all the lead-contaminated soil he could muster, so they could use it to prepare an SRM [Standard Reference Material]  for sale to meet the burgeoning demand?  

 

As another list member has pointed out, lead contamination is ubiquitous.  I painted houses for a living for several years, and can attest that not only chips, but dust, as from when we used electric sanders, traveled far.  In fact, on a windy day and with a taller building, we had to ask people to move their cars from our side of the street, because the Pb-contaminated spatters had sometimes been so visible that litigation ensued.  Dr. Spittler once told me that the half life of Pb in soil is 2000 yr.   My students quantified it many years after it was banned in gas and paint.

Re the original post:

1.  I would think that your workers exposure would be minimal, and 

2. Since most cars still use lead batteries, those sheets should be a marketable commodity on the scrap market. 

Good luck.

 

Steve Stepenuck

 

--
Stephen J. Stepenuck, Ph.D.
Emeritus professor of chemistry
Keene State College
Keene NH 03435-2001
sstepenuck**At_Symbol_Here**ne.rr.com

603.352.7540

 

 

 

On 7/27/19, 10:13 AM, ACS Division of Chemical Health and Safety on behalf of Monona Rossol  wrote:

 

 

And eating veggies from urban home gardens.  do you have a year or other identifier for that article.  Like to get a copy.

 

Monona

-----Original Message-----
From: James Kaufman <jim**At_Symbol_Here**LABSAFETY.ORG>
To: DCHAS-L <DCHAS-L**At_Symbol_Here**PRINCETON.EDU>
Sent: Sat, Jul 27, 2019 6:13 am
Subject: Re: [DCHAS-L] Is lead sheeting a source of lead dust? And-Chemical Exposure question...

Boston EPA found that child lead poisoning went up in the summer (contrary to popular wisdom at the time) because of the lead pain chips in the soil around the homes when children were playing.  ... Jim

James A. Kaufman, Ph.D.

Founder/President Emeritus
The Laboratory Safety Institute (LSI)

A Nonprofit Educational Organization for Safety in Science, Industry, and Education

192 Worcester Street, Natick, MA 01760-2252
508-647-1900  Fax: 508-647-0062 
Cell: 508-574-6264  Res: 781-237-1335
Skype: labsafe; 508-401-7406 

Teach, Learn, and Practice Science Safely

 

 

 

On Fri, Jul 26, 2019 at 6:09 PM Monona Rossol <0000030664c37427-dmarc-request**At_Symbol_Here**lists.princeton.edu> wrote:

Beautiful Dreamer, List to my song.  

 

All the ground around buildings with lead roofs and lead/copper sheeting is usually high in lead.  I know from the building restoration projects I've been involved in.  And there was a big move a few years ago to continue to install lead roofs because they were what was here originally.  Bad idea. There are now stainless steel roofing materials that will last MUCH longer and don't release anywhere near the amounts of metals and no lead.

 

One of the reason they have to replace the lead roofing and flashing every 30 years or so is it has corroded way in spots or has thinned.  Where do you think that lead went?

 

 And the restorers on these projects do NOT publish the data on the soil around the building.  But I've seen it.

 

Monona

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