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Kristi – I would run this one past my Occ. Health Physician, and ask to focus on the reactivity and mechanism of action for these reagents with providing a recommendation regarding the use of calcium gluconate and follow-up medical response, even for limited dermal exposures.
BruceV
From: ACS Division of Chemical Health and Safety [mailto:DCHAS-L**At_Symbol_Here**PRINCETON.EDU] On Behalf Of Kristi Ohr
Sent: Monday, February 26, 2018 6:06 PM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: [DCHAS-L] safety of nucleophilic fluorination reagents
Is anyone else treating nucleophilic fluorination reagents in the same way as HF in terms of precautions and emergency response? I’m not finding any data on the subject aside from recommendations to have calcium gluconate on hand in SDSs.
Thanks,
Kristi
Kristi Ohr, Ph.D.
Chemical Safety Services Manager
Environmental Health and Safety
UMass Amherst
40 Campus Center Way
Draper Hall
Amherst, MA 01003
Office: 413-545-5117
Cell: 413-800-4408
kohr**At_Symbol_Here**ehs.umass.edu
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