DCHAS-L Discussion List Archive
From: TILAK CHANDRA <tilak.chandra**At_Symbol_Here**WISC.EDU>
Subject: Re: [DCHAS-L] safety of nucleophilic fluorination reagents
Date: Tue, 27 Feb 2018 01:02:07 +0000
Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU>
Message-ID: DM5PR06MB3195770D43CA99EC1E19321A88C00**At_Symbol_Here**DM5PR06MB3195.namprd06.prod.outlook.com
In-Reply-To
Hi Kristi:
There
is a low probability of generating HF as a side product during nucleophilic fluorination. By the way which method
researcher is
using for forming the C-F bond? There are various methods available in the
literature for such fluorination.
http://www.scripps.edu/baran/images/grpmtgpdf/Su_May_08.pdf
Good luck.
Tilak
From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**PRINCETON.EDU> on behalf of Kristi Ohr <kohr**At_Symbol_Here**UMASS.EDU>
Sent: Monday, February 26, 2018 5:06:04 PM
To: DCHAS-L**At_Symbol_Here**PRINCETON.EDU
Subject: [DCHAS-L] safety of nucleophilic fluorination reagents
Is anyone else treating nucleophilic fluorination reagents in the same way as HF in terms of precautions and emergency response? I'm not finding any data on the subject aside from recommendations to have calcium gluconate on hand in
SDSs.
Thanks,
Kristi
Kristi Ohr, Ph.D.
Chemical Safety Services Manager
Environmental Health and Safety
UMass Amherst
40 Campus Center Way
Draper Hall
Amherst, MA 01003
Office: 413-545-5117
Cell: 413-800-4408
kohr**At_Symbol_Here**ehs.umass.edu
www.ehs.umass.edu
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