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From: Sara J <saanjohn87**At_Symbol_Here**GMAIL.COM>
Subject: Re: [DCHAS-L] Pentadecafluorooctanoyl chloride.
Date: May 26, 2021 19:46 UTC
Reply-To:
ACS Division of Chemical Health and Safety
In-Reply-To: Re: [DCHAS-L] Pentadecafluorooctanoyl chloride.
Sara Johnson, Ph.D., CCHO
Chemical Hygiene Manager
UNC Chapel Hill Environment, Health & Safety/Risk Management
Tammy,
Good luck getting anything useful out of Sigma. A few years back I was trying to get some clarity from them regarding the classification of tri-n-butylphosphine. According to literature, it has an autoignition temperature of 390 F, but was being classified as pyrophoric. Sigma responded with an updated SDS that replaced the autoignition data with the statement "The substance or mixture is pyrophoric with the category 1."
As an interesting side note, their updated SDS did still provide both oral and dermal LD50 values. I can't recall ever seeing those data points being reported for a material that's truly pyrophoric (nor would I expect to, given the obvious practical and ethical challenges with trying to determine those).
Chris
________________________________
Christopher M. Kolodziej, Ph.D.
Chemical Hygiene OfficerUCLA Environment, Health & Safety | Chemical Safety
Mobile: (310) 261-8611