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Subject: Re: [DCHAS-L] [External] [DCHAS-L] Nitric Acid Disposal

Date: Jul 16, 2021 19:14 UTC

Author: Alyssa Brand <abrand**At_Symbol_Here**LBL.GOV>

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Subject: [DCHAS-L] New articles for ACS Chemical Health & Safety are available online.

Date: Jul 19, 2021 10:37 UTC

Author: Ralph Stuart <membership**At_Symbol_Here**DCHAS.ORG>

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From: Yaritza Brinker <YBrinker**At_Symbol_Here**FELE.COM>

Subject: Re: [DCHAS-L] Nitric Acid Disposal

Date: Jul 16, 2021 20:56 UTC

Reply-To: ACS Division of Chemical Health and Safety

In-Reply-To: Re: [DCHAS-L] Nitric Acid Disposal

Demystify: 

Hmm�

 

Nital is a go-to etchant for steels and it's 1% to 5% Nitric in ethanol or methanol. It is commonly used (and available for purchase) at 2% and 3%. The 20% must have been a typo in the literature.

 

There is an analog to Nital that is 10% nitric in methanol and it's used for etching pure cobalt. If you buy this etchant pre-mixed, it will commonly contain 5% water.

 

Thank you,

 

Yaritza Brinker

260.827.5402

 

From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU> On Behalf Of Daniel Kuespert
Sent: Thursday, July 15, 2021 10:14 AM
To: DCHAS-L**At_Symbol_Here**Princeton.EDU
Subject: Re: [DCHAS-L] Nitric Acid Disposal

 

** External Email **

Acetic acid or acetic anhydride can explode with nitric acid if not kept cold. Experiments demonstrate that mixtures containing more than 50% by weight of nitric acid in acetic anhydride may act as detonating explosives under certain conditions. An indication is given of the percentage mixtures of acetic anhydride-nitric acid which could be detonated using a priming charge and detonator. 

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