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From: James Kaufman <jkaufman**At_Symbol_Here**LABSAFETYINSTITUTE.ORG>
Subject: Re: [DCHAS-L] OSHA materials on Karen Wetterhahn's mercury exposure
Date: Tue, 22 Mar 2022 10:25:44 -0400
Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU>
Message-ID: CAHk9oEQWwvK89YcZp+2V3vDtve3er51zwVPNKd6nm4rVFkWFSA**At_Symbol_Here**mail.gmail.com
In-Reply-To

Demystify: 

Can anyone share a copy of the MSDS that was from the actual DMM supplier? ... Jim

PS. The CSB video said that MSDS recommended latex gloves. I have been unable to locate the MSDS. I did get one from Strem Chemicals from that timeframe but it did not say that.

James A. Kaufman, PhD

Founder/President Emeritus


The Laboratory Safety Institute (LSI)

A Nonprofit Educational Organization for Safety in Science, Industry, and Education

192 Worcester Street, Natick, MA 01760-2252

(O) 508-647-1900 (F) 508-647-0062 (C) 508-574-6264 Skype: labsafe; 508-401-7406

jkaufman**At_Symbol_Here**labsafety.org www.labsafety.org Teach, Learn, and Practice Science Safely






On Tue, Mar 22, 2022 at 10:06 AM Ralph Stuart <ralph**At_Symbol_Here**rstuartcih.org> wrote:
>And wondering about Karen's gloves, were they standard dry-box gloves or did she double glove them inside of the glove-box with another type of glove, as we sometimes double glove with our disposable tactile gloves.

I believe that Dr. Wetterhahn was working in a fume hood rather than a glove box on the occasion of her mercury exposure. I assume that she was using the fume hood to control the fire hazard associated with the dimethyl mercury (flashpoint = 5 degrees C), but the fume hood does not add value with regard to dermal toxicity hazards; and latex gloves add minimial protective value as well. OSHA reports that the dexterity value of the latex gloves led to that choice. I believe that the OSHA presentation on this event suggested that Silvershield gloves were the only appropriate choice at that time.

One of the learning points I take from this story is the challenge of working with chemicals that present multiple hazards while balancing chemical and human factors.

- Ralph

Ralph Stuart, CIH, CCHO
ralph**At_Symbol_Here**rstuartcih.org

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