We do hydrogenations and hydrogenolysis in our lab in quantities of up
to several moles. The equipment is assembled in a hood. Hydrogen is
plumbed into the hood via 1/4" polyethylene tubing cable tied to the
drop ceiling from tanks located elsewhere in the lab. The hydrogen
regulator is set to deliver the lowest feasible pressure and the outlet
valve set to deliver the lowest feasible flow.

The assembled equipment is charged with the reactants and solvents then
evacuated using a small diaphragm pump in the hood through a stopcock. A
two-way stopcock can be used but a three-way stopcock is preferred as it
does not require disconnection of the tubing from the system when
switching between evacuation and fill. Hydrogen is then let into the
evacuated system via the stopcock and fills the balloon. The hydrogen
flow can be shut off at the system using the stopcock. If desired, the
evacuation and fill procedure can be repeated multiple times to flush
residual air from the system.

We use mylar balloons from the Dollar Store as they are more capacious,
stronger, less permeable, and more solvent resistant than rubber
balloons. If you go this route you will need to fit the tubing several
inches into the mouth of the balloon to reach past the internal valve.

The attached photo shows the method we use to connect the balloons to
the system. A gas inlet adapter is fitted with Tygon tubing which then
connects to 1/4" polyethylene tubing. The joint between the two types of
tubing is secured by two wraps of cable tie and sealed with grease. The
tubing extends into the balloon to the point indicated by the arrow. The
joint between the balloon and the 1/4" line is sealed with grease and
fastened by wrapping several times with the ribbon from the balloon.

Best regards
Dave Lane
Chief Science Officer
Artisyn Laboratories



On 7/6/23 12:27 PM, Laura Cunningham wrote:
> Hi all,
>
> Does anyone have recommendations on how to *safely* fill a balloon with hydrogen? The hydrogen tank in this scenario is in an open lab, and the hydrogen filled balloon is for a hydrogenation reaction. The gas tank is located close enough to a fume hood that piping the hydrogen into the fume hood might be feasible. Wondering what other people’s experiences have been with this.
>
> Thanks,
> Laura
>
> Sent from Proton Mail for iOS
>
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