DCHAS-L Discussion List Archive
Date: Mon, 11 Jul 2005 07:16:34 EDT
Reply-To: Labsafe**At_Symbol_Here**AOL.COM
Sender: DCHAS-L Discussion List <DCHAS-L**At_Symbol_Here**LIST.UVM.EDU>
From: Jim Kaufman <Labsafe**At_Symbol_Here**AOL.COM>
Subject: Re: Recent Lab Explosion
Comments: cc: labsafety-l**At_Symbol_Here**siu.edu
In a message dated 7/11/2005 12:02:39 AM Eastern Daylight Time,
LISTSERV**At_Symbol_Here**LIST.UVM.EDU writes:
> I fail to see how gaseous HF can react with steel to produce an excessive
> hydrogen pressure and burst a cylinder:
> 6HF + 2Fe yields 2FeF3 + 3H2
> The product would be FeF3, not FeF2, because fluorine is an excellent
> oxidizing agent. Consequently, if anything, the gas pressure inside the
> cylinder would necessarily be reduced as the HF attacks the iron of the
> cylinder.
>
> It's obvious that the cause of the explosion was the thinning of the
> cylinder wall at one or more locations, NOT the pressure of the hydrogen.
>
> Jay Young
Hey Older (oldest?) Guy,
If Fluorine is such a good oxidizer why doesn't it oxidize iron to the more
oxidized state (+3) just as peroxides do when you kill them with +2 iron
(ferrous sulfate) to make ferric sulfate and reduced peroxides? Why do you believe
that it will stop at the +2 state?
Not quite as old but working on it ... slowly.
James A. Kaufman, Ph.D.
President/CEO
jimkaufman**At_Symbol_Here**labsafety.org
The Laboratory Safety Institute
A Nonprofit International Organization for
Safety in Science and Science Education
192 Worcester Road, Natick, MA 01760-2252
508-647-1900 Fax: 508-647-0062
Cell: 508-574-6264 Res: 781-237-1335
info**At_Symbol_Here**labsafety.org www.labsafety.org
Previous post | Top of Page | Next post
