From: "CHANDRA, Tilak" <tchandra**At_Symbol_Here**FPM.WISC.EDU>
Subject: Re: [DCHAS-L] Extinguishing agent for air/water reactive materials
Date: December 17, 2012 2:37:28 PM EST
Reply-To: DCHAS-L <DCHAS-L**At_Symbol_Here**MED.CORNELL.EDU>
Message-ID: <6F431C2EE2F38D459F5DD28C5B9A10BC0D9B1153**At_Symbol_Here**admin-fpm-exch1>

Hi Debbie:


Clearly the best idea is to avoid having a fire in the first place! Do not discard any wipes contaminated with sodium into trash or sink, before quenching into isopropanol. Leave those wipes into IPA at least one hr. before disposal. This is the standard practice in any pyrophoric metal manipulations in laboratory. Lithium, sodium, and even potassium won't just catch fire unexpectedly (although Na/K alloy will do so). If they do take fire, sand is indeed the best option if Met-L-X is not available.





Tilak Chandra, Ph.D.

Chemical Safety Specialist

EH&S; Chemical Safety

30 East Campus Mall

Madison, WI 53715

Ph. 608-890-0255

Cell:  608-622-9761





From: DCHAS-L Discussion List [mailto:dchas-l**At_Symbol_Here**MED.CORNELL.EDU] On Behalf Of Debbie M. Decker
Sent: Monday, December 17, 2012 12:06 PM
Subject: [DCHAS-L] Extinguishing agent for air/water reactive materials


Good morning:


I’m reviewing an incident report from one of my inorganic synthesis researchers.  A little sodium, wiped off tweezers onto a kimwipe and not properly disposed, that went badly downhill.  No one hurt but it sure got everyone’s heart pounding for a bit.


In the corrective action, the lab worker states they keep LN2 nearby as an extinguishing agent for small air/reactive metals fires (think size of a beaker)..  That just sounds all bad.  In my guidance document, I state that dry sand, Met-L-X, lime, or soda ash are suitable extinguishing agents for small fires.  We have our own fire department and don’t provide Class D fire extinguishers (for a long list of very good reasons).


I’m getting some push back – that using LN2 is commonplace in this lab and the default fire extinguishing agent..






Debbie M. Decker, CCHO

Campus Chemical Safety Officer (soon to be Chemistry Department Safety Manager)
Environmental Health and Safety
University of California, Davis
1 Shields Ave.
Davis, CA  95616
(530)754-7964/(530)681-1799 (cell)

(530)752-4527 (FAX)
Co-Conspirator to Make the World A
Better Place -- Visit and join the conspiracy



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