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Additional Info

Just as a piece of food (which is really just a collection of many chemicals) can spoil or rot (see biodegradable), so can certain chemical substances or mixtures.

For example, when glucose (a form of sugar) is burned in air, it decomposes into carbon dioxide and water. This reaction is also an example of an exothermic combustion reaction:

chemical reaction figure for decomposition of gluocse

See this discussion of thermodynamics for more information about the energy involved in this and other reactions.

Living organisms exploit decomposition reactions in order to live. For example, the digestion of food is an exothermic process, which provides organisms with heat and chemical energy while converting the food to simpler substances that are then used as building blocks within the body or are discarded as waste.

As we live in a dynamic world, many of the everyday objects around us are thermodynamically unstable. Provided the conditions are right, they will decompose all by themselves or with a little help by Nature. Examples include bread, nitroglycerin, lawn clippings and more. Some of these processes generate enough heat on their own to undergo spontaneous combustion!

Certain classes of chemicals such as peroxides, pyrophoric and water-reactive materials can decompose quite readily, releasing so much heat that they can explode or combust. These highly-reactive materials pose serious hazards and should only be handled by experts.

SDS Relevance

The OSHA Hazard Communication Standard (HCS) requires the decomposition temperature to be reported in Section 9 of the Safety Data Sheet and any hazardous decomposition products to be reported in Section 10.

Decomposition can have many effects, each of which is potentially hazardous:

  1. New substances may be formed, some or all of which are explosive, flammable or toxic. Peroxide-forming materials are particularly dangerous.
  2. Decomposition may result in the release of a large amount of heat, possibly resulting in a fire or explosion. The phrase "explosive decomposition" may appear on the Safety Data Sheet (SDS).
  3. Partial decomposition can introduce toxins or other unstable materials as well as degrade the physical properties of the material.
  4. Spontaneous polymerization of the material may occur, changing an easily handled liquid into an insoluble solid (see the BP Amoco case under Further Reading, below). The phrases "self-polymerize" or "auto-polymerize" may appear on the SDS in the storage and transport sections. Some polymerizations may be autocatalytic, meaning that the heat they generate causes the polymerization to accelerate, possibly resulting in an explosive decomposition.

Further Reading

Plastic Keck clips for standard taper joints
Keep your reactions together with these Keck-style standard taper joint clips from Safety Emporium.

See also: HMIS, incompatible chemicals, peroxide, polymerization.

Additional definitions from Google and OneLook.

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