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Subject: Re: [DCHAS-L] Storing ACS-grade acetic acid with ACS grade hydrochloric acid

Date: Feb 29, 2024 16:30 UTC

Author: Kolodziej, Christopher <ckolodziej**At_Symbol_Here**EHS.UCLA.EDU>

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Subject: Re: [DCHAS-L] Storing ACS-grade acetic acid with ACS grade hydrochloric acid

Date: Feb 29, 2024 16:53 UTC

Author: Christa Homenick <christa.homenick**At_Symbol_Here**GMAIL.COM>

From: Monona Rossol <0000030664c37427-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>

Subject: Re: [DCHAS-L] School Incident with Dry Ice

Date: Feb 29, 2024 16:34 UTC

Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU>

Message-ID: <2138046218.1376009.1709224499650**At_Symbol_Here**mail.yahoo.com>

In-Reply-To: <CAFCR6uZVQW5_d3uMzDux2gkr4fjzrup=zbTyLi1NimnOOBxUFA**At_Symbol_Here**mail.gmail.com>

Demystify: 
I've done expert witness in theatrical accidents in Christian churches and youth centers.  Some denominations have traveling troupes of entertainers who do biblical plays and morality productions for services and gatherings and they sometimes use special effects, especially if the play involves the bad guys going to hell at the end.  (I get all the really bizarre and odd safety cases.)

You asked me to "guess where this photo was taken?"   I would guess from the exposed conduit, wiring and small cable, that it is in a basement or some other out of the way location and not where people gather.  It would be better to be in places where people are.

Remember, not all rooms in a building, or all rooms on a single HVAC system, have the same ACH.  That's why we have balancing reports.

That decay formula is really easy to use.  And the best way to use the formula is not on a continual basis, but to shoot a bunch of CO2 from a cylinder or a fire extinguisher into the room you are concerned about and once the CO2 mixes and the numbers settle down, take the second CO2 reading after 15 or 20 minutes.  

The nice thing for this old timer who still has her slide rule is you can type into google "ln 12.345" and log number comes up.  Oy you guys had it easy.

Monona

On Thursday, February 29, 2024 at 11:10:59 AM EST, David EldrEdge <dave.eldredge**At_Symbol_Here**naltic.com> wrote:


Can you guess where this photo was taken?

Check out the fine print on the signs as well.

image.png

You can see the answer here:


BTW... some HVAC engineers recommend using CO2 to measure ACH (air changes per hour). Taking a simple CO2 sensor taking readings before and after saturating the air with CO2, then measuring the decay of the CO2 over time.

See this thread:

I've done a few of these myself, but using people as the source of the CO2:

Youth Fireside 15 Feb 2023 Corrected.jpg

A well ventilated space per CDC should have at least 5 ACH to minimize aerosol disease transmission.

Warm regards,

David EldrEdge
Co-Owner
NALTIC Industrials, LLC
888.891.0077
435.503.4972

Follow us on:
or @nalticx



On Wed, Feb 28, 2024 at 9:34 AM Monona Rossol <0000030664c37427-dmarc-request**At_Symbol_Here**lists.princeton.edu> wrote:
Re, the particular dry ice experiment, I use several cases in my teaching in which people died from doing this kind of nonsense when the ventilation was not up to removing the CO2 rapidly enough. 

I've thought about this kind of problem for decades.  And I've hazcom-trained teachers including science teachers in grade schools and high schools.  You can't ask them to do a risk assessment.  They don't know even the most rudimentary things about how the chemicals interact with our bodies, basic physics, PPE, or ventilation.  In fact, many of them have myths and misconceptions about health and safety that they also pass on to their students.

I've decided that the thing that needs to be done is to teach science along with the toxicology and precautions needed for each chemical used in demonstrations and in labs -- AT THE TIME THE STUDENT FIRST ENCOUNTERS THE CHEMICALS.  

In plain speak:  No person completes any art, theater, or science curriculum in which chemicals or chemical products were used who doesn't know;
 
a) where their lungs are and how they work, and the same with all major organ systems; 
b) enough physics to know how gases, vapors, particles of all sizes behave in the air;
c) how the body absorbs chemicals and what they do there;
d) how to select and properly use PPE for those chemicals;
e) know the basics of ventilation including how various types of fume hoods work and why (in art, how kiln, welding, and other local exhaust systems work and why); and
f)  the basic occupational regulations that apply to what they do.

And schools need to stop teaching science in buildings that are not equipped with the proper ventilation and equipment.  I offer into evidence the fact that my 40-hour course, starting with the first time I taught it in 1980, would take hold in a school and then be dropped from the curriculum within a year or two.  The reason always was that, if the course is taught properly, students soon are able to realize that their labs and studios are not properly equipped and their teachers know less about health and safety than they now do.  In one university three years after the course was instituted, there were 5 workers' comp cases and two personal injury law suits filed from teachers and students who claimed harm from the conditions in the hell-hole of a building they were in.  The school built a new building -- that was better, but still not properly equipped.  This leads me to conclude that administrators also should be required to take the course.

Safety cannot be left up to individual teachers or a couple of tool box lectures. It needs to be a formal, for credit, required course for a minimum of a semester.

Monona

On Sunday, February 25, 2024 at 11:51:48 AM EST, Monique Wilhelm <biocmst**At_Symbol_Here**gmail.com> wrote:



I do not have any additional details.  Although I do suggest anyone working with hazardous materials with groups (or otherwise) to do a risk assessment and have appropriate controls in place as well as plans for any incidents that could occur.
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