From:
Samuella Sigmann <sigmannsb**At_Symbol_Here**RETIRED.APPSTATE.EDU>
Subject:
Re: [DCHAS-L] Storing ACS-grade acetic acid with ACS grade hydrochloric acid
Date:
Feb 29, 2024 17:38 UTC
Reply-To:
ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU>
Message-ID:
<18876b22-b1cd-4808-bcbd-8e13ba38a63f**At_Symbol_Here**retired.appstate.edu>
In-Reply-To:
<CAAszpkxXPxivmhNPiYWmXESu-+_RKKjM-ig9Df2PrWzGAB0rOQ**At_Symbol_Here**mail.gmail.com>
Hey Margaret - This is the kind of question that I look to CAMEO to
answer. When mixed in silico you get the following for 12M HCl and
glacial acetic. Of course, in storage this would assume both bottle
broke. Some want glacial stored in flammable cabinets.
Sammye
Reactivity Alerts
Hazard Predictions
ACETIC ACID,
GLACIAL mixed with
HYDROCHLORIC
ACID, SOLUTION
Incompatible 
-
Flammable: Reaction products may be flammable
-
Generates gas: Reaction liberates gaseous
products and may cause pressurization
-
Generates heat: Exothermic reaction at ambient
temperatures (releases heat)
-
Toxic: Reaction products may be toxic
- May produce the following gases:
- Carbon Monoxide
- Carbon Dioxide
On 2/28/2024 8:49 PM, Margaret Rakas
wrote:
Good evening--
The chemical compatibility charts I've reviewed indicate
inorganic acids should be stored separately from organic
acids. This makes sense if a lab is storing a variety of both
types. We all know what happens with nitric acid and organic
acids..
However, we're renovating a geology lab that uses mostly
hydrochloric acid and occasionally uses acetic acid, both ACS
grade (which are further diluted before using to digest rock
or soil samples). I have reviewed both Sigma and Fisher SDS's
for these two materials, and it does not seem to me that
storing several 500mL-1 Liter bottles of each together in a
corrosives cabinet would be incompatible storage or create a
safety risk. Storing them with caustics, permanganates,
oxidizing acids, metals--that would be a concern, but this lab
doesn't use any of these incompatible reagents.
Thoughts? Am I missing something?
Many thanks as always-
Margaret
--
Margaret A. Rakas, Ph.D.
Lab Safety & Compliance Director
Clark Science Center
Smith College
413-585-3877 (p)
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