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Subject: Re: [DCHAS-L] Inquiry on Isoamyl Alcohol as a Peroxide Former

Date: Mar 21, 2025 15:59 UTC

Author: Samuella Sigmann <00001d2fb4580b5b-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>

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Subject: [DCHAS-L] Spring Professional Workshop Series

Date: Mar 22, 2025 23:13 UTC

Author: Denlinger, Kendra <00002018fc81863a-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>

From: Tammy M Lutz-Rechtin <00001eefcacf32aa-dmarc-request**At_Symbol_Here**LISTS.PRINCETON.EDU>

Subject: Re: [DCHAS-L] Inquiry on Isoamyl Alcohol as a Peroxide Former

Date: Mar 21, 2025 16:47 UTC

Reply-To: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU>

Message-ID: <SA0PR04MB74494C4B127BFB0D06945B61BADB2**At_Symbol_Here**SA0PR04MB7449.namprd04.prod.outlook.com>

In-Reply-To: <ea06a47c-e290-42f9-b79d-6ad1fb76de0a**At_Symbol_Here**retired.appstate.edu>

Demystify: 

This is probably the university of minnesota’s list. 7.5 Peroxide-Forming Chemicals and Highly Reactive Substances | UMN University Health & Safety  It’s wonderful resource!  However, the incident only involves testing of samples in a lab. I have the original article. I am really wondering what these production facilities are doing because it appears as if its status as a peroxide former is being completely ignored.

Tammy

 

From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU> On Behalf Of Samuella Sigmann
Sent: Friday, March 21, 2025 10:59 AM
To: DCHAS-L**At_Symbol_Here**Princeton.EDU
Subject: Re: [DCHAS-L] Inquiry on Isoamyl Alcohol as a Peroxide Former

 

Can you share the provenance of this Google Sheet?
Thanks,
Sammye

On 3/21/2025 11:20 AM, Pavlak, Edmund J wrote:

Here is a link I frequently use:

Peroxide Forming Chemical Data - Google Sheets

Isoamyl alcohol is on line 185.

There is also a reference link in column G box of the line 185 to an ACS publication.

 

Hope this helps.

 

Joe Pavlak

From: ACS Division of Chemical Health and Safety <DCHAS-L**At_Symbol_Here**Princeton.EDU> On Behalf Of Tammy M Lutz-Rechtin
Sent: Thursday, March 20, 2025 6:09 PM
To: DCHAS-L**At_Symbol_Here**Princeton.EDU
Subject: [DCHAS-L] Inquiry on Isoamyl Alcohol as a Peroxide Former

 

Dear Colleagues,

 

Isoamyl alcohol (3-Methyl-1-butanol) is classified as a Class B peroxide former, as confirmed by multiple sources. However, I have yet to find case studies or documented incidents where it has caused issues beyond its inherent flammability. Given its recent designation as a “green” and renewable chemical, with proposed recycling and bioproduction initiatives, I am interested in understanding how industry currently manages isoamyl alcohol in this context.

 

If anyone has insights on industry handling practices or case studies where isoamyl alcohol has posed peroxide-related risks, I would greatly appreciate your input. My intent is to use this information to help establish policies with my colleagues in the bio-based sector.

 

Thank you for your time and expertise.

 

Regards,

Tammy Rechtin

 

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******************************************************************************

 

Samuella B. Sigmann, MS, NRCC-CHO

ACS Committee on Chemical Safety, Chair 2022-2024

ACS Fellow, 2023

ACS Division of Chemical Health & Safety, Fellow & 2019 Chair,

Appalachian State University, Retired

Phone: 336 877 5147

Email: sigmannsb**At_Symbol_Here**retired.appstate.edu

 

 

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