May 12, 2003 - Determination of airborne concentrations of methylene chloride; protection of employees covered by 1910.1052.May 12, 2003 - Methylene chloride; Air conc. det. and protection of employees covered by 1910.1052.
The Home page of ILPI's Safety Data Sheet (SDS) Resource, the leader in SDS information since 1995!
The history and philosophy behind this resource.
A curated collection of books and reference materials concerning Safety Data Sheets and closely related topics.
Paste your plain text SDS into the SDS-Demystifier, and it will be converted into a hypertext-enriched document with links to detailed explanations of each key term.
An extensive list of frequently asked questions about Safety Data Sheets including regulations, content, compliance, and more.
A humorous take on Safety Data Sheet jargon. Fill in the blanks on our entry form to generate a personalized Unsafety Data Sheet to share with your coworkers.
Since 1995, we've maintained this massive curated list of the best places to find Safety Data Sheets on the Internet.
Way more than a glossary, this hypertext-enhanced resource covers hundreds of SDS-related terms and expert knowledge. Each entry includes both the SDS relevance and links to additional authoritative resources.
Archived results of Safety Data Sheet related polls taken by some of our millions of site visitors
You are here! The OSHA regulations behind SDS regulations, including the inspection guidelines and over 400 official interpretations letters under the Hazard Communication Standard
Commercial suppliers of SDS authoring and management software as well as cloud compliance services.
Commercial companies that will create SDS's for your specific needs as well as SDS translation companies.
Safety signs, banners, and scoreboards? Get yours at Safety Emporium!
Title: 05/12/2003 - Determination of airborne concentrations of methylene chloride; protection of employees covered by 1910.1052.
OSHA requirements are set by statute, standards and regulations. Our interpretation letters explain these requirements and how they apply to particular circumstances, but they cannot create additional employer obligations. This letter constitutes OSHA's interpretation of the requirements discussed. Note that our enforcement guidance may be affected by changes to OSHA rules. Also, from time to time we update our guidance in response to new information. To keep apprised of such developments, you can consult OSHA's website at https://www.osha.gov.
May 12, 2003
Kenneth L. Spears, Captain
Fleet & Property Management Florida Highway Patrol
2900 Apalachee Parkway
Neil Kirkman Building
Tallahassee, FL 32399-0500
Dear Mr. Spears:
Thank you for your February 21 letter to the Occupational Safety and Health Administration's (OSHA's) Directorate of Enforcement Programs. You have questions about an aerosol subject restraint (ASR) spray containing methylene chloride, identified as [product identity removed], that is manufactured by [manufacturer's name removed]. This letter constitutes OSHA's interpretation only of the requirements discussed and may not be applicable to any question not delineated within your original correspondence. Our replies to your paraphrased questions and scenarios are provided below.
Scenario 1: Florida Highway Patrol sprays its employees with [manufacturer's name removed] methylene chloride-containing ASR ([product identity removed]) in training, prior to being issued this product for use during law enforcement activities.
Reply: No, because the Occupational Safety and Health Act of 1970 (the Act), which established OSHA, excludes states and political subdivisions of states from coverage, except in states which administer federally-approved state plans. Twenty-six states and territories currently administer such plans, but Florida is not among them. Since Florida Highway Patrol employees are employees of the State of Florida, they are not covered by OSHA requirements, including those in the Hazard Communication Standard.
Reply: Yes. Please refer to the introduction for OSHA's methylene chloride standard, 29 CFR 1910.1052.
Question 3:Is the amount of methylene chloride cited in the [manufacturer's name removed] correspondence consistent with permissible exposure levels set by OSHA?
Reply: Please be aware that the airconcentration levels of methylene chloride provided by [manufacturer's name removed] are not indicative of the actual airborne exposure to methylene chloride that an individual sprayed with [product identity removed] experiences. [manufacturer's name removed] provided you with the uniform air concentration values of methylene chloride that would be produced if [product identity removed] were sprayed into an 800 cubic foot, unventilated, air-tight room. That is, 3.25 parts per million (ppm) for a 1-second burst of spray, 9.75 ppm for a 3-second burst of spray, and 97.5 ppm for a 30-second burst of spray, are the concentrations of methylene chloride that would exist at every point in the room after the spray has completely diffused.
Initially, the air concentration of methylene chloride at the point where the vaporization takes place is going to be much higher than, for example, the 3.25 ppm that [manufacturer's name removed] reports for a 1-second burst of spray. Therefore, the actual air concentration of methylene chloride in a sprayed individual's breathing zone should be measured by sampling and analyzing the air within his or her breathing zone.1
Question 4: Does our application of this product require compliance with any OSHA rules cited in the "Technology Bulletin"? If so, can you provide specific steps required to be taken?
Reply: No. The Florida Highway Patrol is not required to comply with any OSHA rules because, as we stated in our reply to Question 1, it is not a covered employer under the Act. However, employers covered by either Federal OSHA or a State plan must comply with the methylene chloride and hazard communication standards when using this product.
Many of our visitors use these weather-resistant SDS storage boxes like this one. We have 3 different sizes available at Safety Emporium.
Some of the steps that the covered employers must take include:
determine each employee's exposure to airborne methylene chloride;
notify employees of their levels of exposure to methylene chloride;
ensure that employees do not receive airborne methylene chloride exposures that exceed either of the permissible exposure limits (PELs);
establish records of employee exposures to methylene chloride;
maintain workplace copies of an ASR spray's MSDS that incorporates the required methylene chloride information and ensure that it is readily accessible to employees during each work shift; and
ensure that the ASR spray cans are labeled, tagged, or marked to relate that they contain methylene chloride and that methylene chloride is a carcinogen.
Note: The methylene chloride standard contains within it references to portions of the hazard communication standard that apply to methylene chloride. Moreover, 29 CFR 1910.1052(k) specifies the hazards associated with methylene chloride that must be communicated on labels and in material safety data sheets (MSDSs) in accordance with the requirements of the hazard communication standard. Please refer to the methylene chloride and hazard communication standards for more details on their requirements.
Thank you for your interest in occupational safety and health. We hope you find this information helpful. OSHA requirements are set by statute, standards, and regulations. Our interpretation letters explain these requirements and how they apply to particular circumstances, but they cannot create additional employer obligations. This letter constitutes OSHA's interpretation of the requirements discussed. Note that our enforcement guidance may be affected by changes to OSHA rules. Also, from time to time we update our guidance in response to new information. To keep apprised of such developments, you can consult OSHA's website at https://www.osha.gov . If you have any further questions, please feel free to contact the Office of Health Enforcement at 202-693-2190.
Sincerely,
Richard E. Fairfax, Director
Directorate of Enforcement Programs
[Corrected 11/9/2004]
1 OSHA defines the breathing zone as an 18" diameter sphere around the employee's head.