05/23/2008 - Storage and use of compressed gas cylinders; whether cylinder is considered an oxidizing compressed gas or oxygen cylinder.

Interactive Learning Paradigms, Incorporated


The Home page of ILPI's Safety Data Sheet (SDS) Resource, the leader in SDS information since 1995!
The history and philosophy behind this resource.
A curated collection of books and reference materials concerning Safety Data Sheets and closely related topics.
Paste your plain text SDS into the SDS-Demystifier, and it will be converted into a hypertext-enriched document with links to detailed explanations of each key term.
An extensive list of frequently asked questions about Safety Data Sheets including regulations, content, compliance, and more.
A humorous take on Safety Data Sheet jargon. Fill in the blanks on our entry form to generate a personalized Unsafety Data Sheet to share with your coworkers.
Since 1995, we've maintained this massive curated list of the best places to find Safety Data Sheets on the Internet.
Way more than a glossary, this hypertext-enhanced resource covers hundreds of SDS-related terms and expert knowledge. Each entry includes both the SDS relevance and links to additional authoritative resources.
Archived results of Safety Data Sheet related polls taken by some of our millions of site visitors
You are here! The OSHA regulations behind SDS regulations, including the inspection guidelines and over 400 official interpretations letters under the Hazard Communication Standard
Commercial suppliers of SDS authoring and management software as well as cloud compliance services.
Commercial companies that will create SDS's for your specific needs as well as SDS translation companies.

Safety signs, banners, and scoreboards? Get yours at Safety Emporium!

XXXPrevNext
Title: 05/23/2008 - Storage and use of compressed gas cylinders; whether cylinder is considered an oxidizing compressed gas or oxygen cylinder.
Record Type: InterpretationStandard Number: 1910.101, 1910.101(a), 1910.101(b), 1910.1200, 1910.1450
    May 23, 2008

    Mr. Charles Tricomi
    Consolidated Edison of New York
    31-01 20th Ave. Bldg. 136 2nd Fl.
    Astoria, NY 11105

    Dear Mr. Tricomi:

    Thank you for your letter of September 18, 2007, to the Occupational Safety and Health Administration's (OSHA's) Directorate of Enforcement Programs (DEP). You had questions concerning standards applicable to the storage and use of compressed gas cylinders. Your paraphrased questions and our response follow.

    Scenario: I have two compressed cylinders used for laboratory calibration of gas detectors. One cylinder contains 20.9% oxygen (balance nitrogen); the other contains 100% methane. The volume of each cylinder is approximately 2 cubic feet, and they are pressured at 2000 psi.

    Question #1: What standards apply to the use, storage, and handling of these cylinders?

      Response #1: The handling, use, and storage of compressed gas cylinders in applications other than welding and cutting in general industry workplaces is governed by OSHA's Compressed gases standard, 29 CFR 1910.101. The standard, at 29 CFR 1910.101(a), requires that gas cylinders be visually inspected to determine that they are in safe condition.1
      The standard further states, in §1910.101(b), that "the in-plant handling, storage, and utilization of all compressed gases in cylinders...shall be in accordance with Compressed Gas Association (CGA) Pamphlet P-1-1965." We note that there are more recent versions of the industry consensus standards that are referenced in §1910.101.2 If the more recent consensus standards address hazards associated with compressed gases that are not addressed in the CGA pamphlets referenced in the standard, §1910.101, §1910.1200, or any other applicable OSHA standard, the more recent consensus standards may provide support for a citation alleging a violation of the OSH Act's general duty clause, 29 USC 651(a)(1). If an employer is not in compliance with the requirements of an OSHA standard but is complying with the requirements of a current consensus standard that clearly provides equal or greater employee protection, the violation of OSHA's requirement will be treated as a de minimis violation. De minimis violations are those having no direct or immediate relationship to safety and health and result in no citation, penalty, or requirement to abate.

      		Cylinder tag

      Get gas cylinder accessories such as tags, signs, and storage cabinets at Safety Emporium.

      You stated in your letter that you are using these cylinders in a laboratory environment. OSHA's laboratory standard, §1910.1450, Occupational exposure to hazardous chemicals in laboratories, defines "hazardous chemical" as one that has been established to produce acute or chronic health effects in exposed employees. While methane is an asphyxiant, it does not produce the acute or chronic health effects described in 1910.1200 Appendix A to which the lab standard refers. However, methane does present an explosion or flammability hazard. Therefore, OSHA's Hazard communication standard, §1910.1200, would apply. The Hazard communication standard requires, among other things, that employees receive training with regard to the hazards associated with the chemicals with which they work, how to detect the presence of those chemicals in the workplace, and the measures required to protect themselves from those hazards.

    Question #2: Is a cylinder that contains 20.9% oxygen (balance nitrogen) considered an oxygen cylinder or an oxidizing compressed gas?

      Response #2 The cylinder contains 20.9% oxygen and 79.1% nitrogen, which is essentially compressed air.3 While air is technically an oxidizer, compressed air presents no greater oxidation hazard than that of the atmospheric air already present in the workplace. This position was reflected in OSHA's comparison of its Hazard communication standard, 29 CFR 1910.1200, with the Global Harmonization System (GHS) for the Classification and Labeling of Chemicals (available on OSHA's website at https://www.osha.gov/dsg/hazcom/GHSOSHAComparison.html). This document notes, in Section 2.4.2, that "[a]rtificial air containing up to 23.5% vol. oxygen % may be regarded as not oxidizing for some regulatory purposes (e.g. [sic] transport)." Therefore, the cylinder containing 20.9% oxygen would not be considered an oxygen cylinder or an oxidizing compressed gas for the purposes of 29 CFR 1910.101.

    Thank you for your interest in occupational safety and health. We hope you find this information helpful. OSHA requirements are set by statute, standards, and regulations. Our interpretation letters explain these requirements and how they apply to particular circumstances, but they cannot create additional employer obligations. This letter constitutes OSHA's interpretation of the requirements discussed. Note that our enforcement guidance may be affected by changes to OSHA rules. Also, from time to time we update our guidance in response to new information. To keep apprised of such developments, you can consult OSHA's website at https://www.osha.gov.

    Sincerely,

    Richard E. Fairfax, Director
    Directorate of Enforcement Programs

    1 The standard, at §1910.101(a), requires the visual inspections to be conducted in accordance with the Hazardous Materials Regulations of the Department of Transportation (DOT) (49 CFR parts 171-179 and 14 CFR part 103), where appropriate. If these standards are not applicable, the standard requires that "visual and other inspections shall be conducted in accordance with Compressed Gas Association pamphlets C-6-1968 and C-8-1962..." [ back to text ]

    2 CGA Pamphlets C-6-2007, Standards for Visual Inspection of Steel Compressed Gas Cylinders; C-8-2005, Standard for Requalification of DOT-3HT, CTC-3HT, and TC-3HTM Seamless Steel Cylinders; and P-1-2006, Safe Handling of Compressed Gases in Containers.[ back to text ]

    3 CGA Specification G-7.1-2004, Commodity Specification for Air, indicates that compressed air is a blend of oxygen (ranging from 19% to 23%) and nitrogen (balance of the volume), and, in some cases, other trace gases.[ back to text ]

    		storage cabinet

    Gas cylinder storage cabinets and more are available from Safety Emporium.

The original official public domain version of this document is available from OSHA at XXXOSHAURL.