Interactive Learning Paradigms, Incorporated


The Home page of ILPI's Safety Data Sheet (SDS) Resource, the leader in SDS information since 1995!
The history and philosophy behind this resource.
A curated collection of books and reference materials concerning Safety Data Sheets and closely related topics.
Paste your plain text SDS into the SDS-Demystifier, and it will be converted into a hypertext-enriched document with links to detailed explanations of each key term.
An extensive list of frequently asked questions about Safety Data Sheets including regulations, content, compliance, and more.
A humorous take on Safety Data Sheet jargon. Fill in the blanks on our entry form to generate a personalized Unsafety Data Sheet to share with your coworkers.
Since 1995, we've maintained this massive curated list of the best places to find Safety Data Sheets on the Internet.
Way more than a glossary, this hypertext-enhanced resource covers hundreds of SDS-related terms and expert knowledge. Each entry includes both the SDS relevance and links to additional authoritative resources.
Archived results of Safety Data Sheet related polls taken by some of our millions of site visitors
You are here! The OSHA regulations behind SDS regulations, including the inspection guidelines and over 400 official interpretations letters under the Hazard Communication Standard
Commercial suppliers of SDS authoring and management software as well as cloud compliance services.
Commercial companies that will create SDS's for your specific needs as well as SDS translation companies.
Safety Emporium has thousands of OSHA safety signs and more

Safety signs, banners, and scoreboards? Get yours at Safety Emporium!

OSHA Hazard Communication Letters of Interpretation

Investigation of chromium in photocopier toner

Issued
Record type
Interpretation
Historical standard
1910.1200, original 1983 rule (PDF)
Current standard
HCS 2024, as amended

ILPI assessment: Interim investigation letter is not a product-safety determination

This letter predates the September 1987 effective date of the expanded HCS. The original 1983 standard is now obsolete. Its conditional point remains relevant: actual chemical identity, hazards, and potential exposure must be evaluated. It reports an investigation in progress in 1987; it does not establish the composition or safety of a current Canon or other toner product.

Under the current HCS, apply hazard classification, mixture criteria, carcinogenicity criteria, and SDS ingredient disclosure. Where applicable, chromium(VI) hazard communication also addresses cancer. Total chromium, a particular chromium compound, and chromium(VI) are not interchangeable findings; the incoming correspondent's allegations below are not OSHA's final determination.

The related February 16, 1988 response also requires historical context and carries an OSHA archive notice. Neither letter should substitute for current product-specific evidence or the applicable current standards.

Last reviewed: .

About this ILPI assessment

This comparison with current requirements is not a finding that OSHA has formally withdrawn this letter. This assessment reflects editorial judgment informed by human review and AI assistance. It is an opinion, may contain errors or omissions, and is not an official OSHA determination. For guidance on how OSHA requirements apply to your circumstances, contact your local OSHA office.

OSHA's notice about interpretation letters

The following notice is published on OSHA's interpretation pages; it is general guidance, not a letter-specific withdrawal notice.

OSHA requirements are set by statute, standards and regulations. Our interpretation letters explain these requirements and how they apply to particular circumstances, but they cannot create additional employer obligations. This letter constitutes OSHA's interpretation of the requirements discussed. Note that our enforcement guidance may be affected by changes to OSHA rules. Also, from time to time we update our guidance in response to new information. To keep apprised of such developments, you can consult OSHA's website at https://www.osha.gov.

Source: OSHA's original letter page.

August 25, 1987

Mr. Desmond Bond
Desmond Bond, Inc.
Energy & Environment
3940 Tallowtree Place
Fairfax, Virginia 22033

Dear Mr. Bond:

This is in response to your letter of August 6, regarding the presence of chromium in monocomponent photocopier toner.

GHS Safety Data Sheets Poster

Ensure your workers are trained with safety posters and more at Safety Emporium.

Our New York Regional Office is still investigating your previous letter alleging that toner cartridges manufactured and sold by Canon U.S.A., Inc., contain chromium. Until the investigation is completed we cannot give you a final response.

[ILPI note: This is an interim 1987 response, not a present finding about a toner product. Historical standard: 1910.1200, original 1983 rule (PDF). Current counterparts: mixture classification, carcinogenicity criteria, ingredient disclosure, and chromium(VI) hazard communication. The incoming letter below states the correspondent's allegations.]

If our investigation indicates that the product contains hexavalent chromium and that employees covered by the standard are potentially exposed, then the toner would be subject to the requirements of the Hazard Communication Standard. Under the Hazard Communication Standard a warning of carcinogenicity may be required on the label. In addition, the material safety data sheet would need to address the carcinogenic effects of hexavalent chromium compounds to detail.

As soon as our investigation is completed we will contact you again with a full response. If you have any further questions in the interim, please feel free to contact me again.

Sincerely,

John A. Pendergrass
Assistant Secretary


August 6, 1987

Mr. John Pendergrass
Assistant Secretary
Occupational Safety and Health Administration
U.S. Department of Labor
200 Constitution Avenue, N.W.
Washington, D.C. 20210

Dear Mr. Pendergrass:

On June 3, 1987, I wrote to you regarding the presence of chromium in monocomponent photocopier toner. Since then, my client has continued to fund analyses by independent analytical laboratories to confirm the initial findings which I transmitted to you. This letter is to advise you of the outcome of that effort and to reiterate the inquiries of my earlier letter.

Subsequent analyses have confirmed the presence of chromium in samples of a monocomponent photocopier toner manufactured by one of my client's competitors, and in a similar product formerly manufactured by my client. The levels of hexavalent chromium detected in these analyses vary widely, but have, in general, been considerably lower than the level presented in the initial laboratory report (copy already forwarded to you).

Uncertainly as to the precise quantity of hexavalent chromium in the samples has arisen for a number of reasons, but chiefly, (i) because of the nature of the chromium substance itself, a chelate, and, (ii) because of the absence of a testing protocol that can detect with certainly all hexavalent chromium present.

Nevertheless, the hazards involved with use of toners which contain chromium do remain a subject of great concern. The enclosed toner label (Attachment 1) specifies that the hazardous Ingredient in the toner is a chromium salt. The particular chromium species bears the CAS No. 72869-85-3; the name given to that substance, as officially noted by Chemical Abstracts Service, is "chromate". That group of chromium salts (chromates) is declared by authoritative toxicity sources to be carcinogenic. (See Attachment 2)

NFPA Self-Laminating Labels - Chemical Name, Common Name, Manufacturer
Safety Emporium carries NFPA signs and labels like these ones. Plus a whole lot more!

My client, has ceased manufacture and marketing of the chromium-containing toner, and is attempting to market a toner which does not contain chromium. Therefore, my client remains seriously interested in obtaining OSHA's advice concerning the Agency's Hazard Communication requirements. It would be most helpful to my client's planning basis if, using the attached label (Attachment 1) and MSDS (Attachment 3) as examples, you would advise specifically what information OSHA does require for a product label and MSDS for a chromium-containing toner.

I do look forward to receiving your Agency's response to the foregoing issues concerning chromium, labeling, and MSDS as soon as possible.

Sincerely,

Desmond Bond

Attachments


In addition to concerns regarding the chromium in the chemical species named on the label (Salicylic Acid Chromium Chelate) the following facts should be noted:

  1. Salicylic Acid Chromium Chelate is a derivative of salicylic acid. Salicylic acid (CAS #69-72-7, formula C7H6O3) is a fire and explosion hazard, a dermal and an occular irritant, and, in quantity, a lethal ingestant. (MSDS available from OSHA, Dec. 1985);
  2. "Salicylic acid is a hazardous chemical under criteria of the OSHA Hazard Communication Standard." (Chemical Products Synopsis, Feb. 1987);
  3. Kirk-Othmer: Encyclopedia of Chemical Technology 20 (3rd Edit., 1982) documents "Health and Safety Factors (Toxicology)" and "Toxicity and First Aid" features on salicylic acid. (pp. 508,9).

The original official public domain version of this document is available from OSHA at https://www.osha.gov/laws-regs/standardinterpretations/1987-08-25.