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Heavy Metal

Definition

The term heavy metal refers to any metallic chemical element that has a relatively high density and is toxic, highly toxic or poisonous at low concentrations. Examples of heavy metals include mercury (Hg), cadmium (Cd), arsenic (As), chromium (Cr), thallium (Tl), and lead (Pb).



"Heavy metal" also refers to a form of rock and roll music, but such references are unlikely to be found in an MSDS.

Additional Info

Heavy metals are dangerous because they tend to bioaccumulate. For example, marine organisms can consume a particularly dangerous form of mercury called methylmercury. When fish eat these organisms, the methylmercury is not excreted, but is instead retained in bodily tissues. The older the fish and the more contaminated organisms it has consumed, the greater the amount of methylmercury in its tissues. When another fish eats the first fish, the accumulated methylmercury is passed up the food chain, eventually becoming hundreds or thousands of times its original concentration. Any organism at the top of the food chain (humans, polar bears etc.) faces a serious risk of mercury poisoning by eating such fish.

Here's an example of cadmium bioaccumulation that is threatening wildlife in the Rocky Mountains.

Lead poisoning is another example of heavy metal poisoning. Lead is neurotoxic, so individuals whose body is still developing (such as children or developing fetuses) are most at risk. While some aspects of lead poisoning are reversible in adults, in children this can interfere with normal development, cause irreparable brain damage, or kill.

Because of the recognized dangers of these elements, OSHA has established workplace guidelines for the following heavy metals:

29 CFR 1910.1018 Inorganic Arsenic. See also: Appendix A - Inorganic arsenic substance information sheet . Medical surveillance guidelines. Offical Interpretations for this standard. 29 CFR 1910.1027 Cadmium. See also: Appendix A - Substance Safety Data Sheet. Appendix B - Substance Technical Guidelines. Appendix E - Cadmium in Workplace Atmospheres. Appendix F - Nonmandatory Protocol for Biological Monitoring. Official Interpretations for this standard. 29 CFR 1910.1025 Lead. See also: Appendix A - Substance data sheet for occupational exposure. Appendix B - Employee standard summary. Appendix C - Medical surveillance guidelines. Official Interpretations for this standard.

Get Title 29 of the US Federal Code in searchable hypertext PDF format on CD-ROM from Safety Emporium.

Heavy metal exposure occurs through three primary routes:

1. Inhalation. Common examples include workers scraping or sanding lead paint and workers in factories where heavy metals are melted and processed. In the days before leaded gasoline was banned, those living alongside heavily traveled roads faced significant exposure through tailpipe emissions.

2. Ingestion. The leading cause of lead poisoning in children is eating old paint chips. A major source of elevated mercury levels in humans comes from eating contaminated fish. And people can drink arsenic from wells contaminated by arsenic-containing pesticides.
3. Skin absorption. Day to day contact with heavy metals can cause poisoning. Dermal exposure is a serious concern for workers in fields where the irrigation water contains naturally-occuring arsenic (such as Asian rice paddies). See Environ. Sci. Technol., DOI: 10.1021/es903667.

This safety wall poster from Safety Emporium uses heavy metal humor to reinforce good workplace habits.

MSDS Relevance If you are occupationally exposed to heavy metals, your workplace should have written protocols in place to minimize your exposure. A variety of controls such as eliminating or minimizing the use of such materials, the use of fume hoods, respirator requirements, medical monitoring and more may be required. Presumably, employers should be taking care to ensure that no worker is exposed to potentially harmful levels of any substance. However, this is not always the case, so be vigilant. Be sure to read the MSDS for any heavy-metal containing material very closely. It should describe the symptoms of poisoning and chronic effects of exposure. Heavy metals are fetotoxic, so women of child-bearing age should avoid any exposure to heavy metals. Note: the U.S. Supreme Court has declared it illegal under the Pregnancy Discrimination Act for employers to bar women from jobs that may expose them to lead or other toxins! See this OSHA Interpretation Letter on the ruling or this EEOC PDA fact sheet for more information. Further Reading See the links above under Additional Info for workplace regulations. ATSDR has a ToxFAQ's on arensic, cadmium, chromium, lead, mercury, thallium and more. Mercury in the laboratory. Explains the dangers of elemental mercury and includes other links. This Canadian site has nice info about occupational and non-occupational exposure to cadmium. Case Studies in Environmental Medicine: Lead Toxicity at the US CDC. Toxicity, Heavy Metals at eMedicine.com, a resource for health professionals. Metals entry at Toxipedia covers several metals with user-edited writeups. Lead clean-up in Nigerian village is life-or-death race against time (2010) is about the world's worst recorded outbreak of lead poisoning. See also: alopecia, nephrotoxin, reproductive toxin. Additional definitions from Google and OneLook.

Disclaimer: The information contained herein is believed to be true and accurate, however ILPI makes no guarantees concerning the veracity of any statement. Use of any information on this page is at the reader's own risk. ILPI strongly encourages the reader to consult the appropriate local, state and federal agencies concerning the matters discussed herein.