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|Do not confuse this term with the word alkaline which refers to a basic substance (one with a pH greater than 7) or with alkaline earth.|
In their elemental forms, the alkali metals are all soft, ductile, malleable substances that can be easily cut with a knife or drawn into a wire. Although these are shiny when cut, they almost immediately tarnish in air.
Alkali metals are quite reactive towards air and water, with increasingly dangerous reactivity as one moves down the column from Li to Cs. The reaction with water can be summarized by the chemical equation below where M = an alkali metal.
2 M(s) + 2 H2O 2 M+(aq) + 2 HO-(aq) + H2(g)
Get your water-reactive signs and labels at Safety Emporium.
The heat generated by this reaction is sufficient in most cases to ignite the hydrogen gas (H2) that is evolved in the reaction. This can result in a powerful explosion depending on the amount and surface area of the alkali metal. Elemental potassium and cesium are particularly dangerous in this regard; even one gram can cause a serious hazard. When working with alkali metals, be sure you have a fire extinguisher that is approved for Class D fires.|
Because of their water-reactive and/or pyrophoric nature, alkali metals are usually stored under an inert atmosphere and/or mineral oil. This also reduces the rate of formation of dangerous peroxides. Note: lithium should not be stored under nitrogen because the two can react to form lithium nitride, Li3N.
Finally, note there is a great difference between an alkali metal and an alkali metal cation. For example, (elemental) sodium metal, Na, is quite dangerous to work with, whereas sodium chloride (which contains the sodium ion, Na+, and chloride ion, Cl-) is common table salt. Then again, excessive dietary salt intake is associated with hypertension (high blood pressure).
Do not work with alkali metals unless you have had special training from someone who is experienced in working with these materials. Most accidents involving alkali metals tend to occur when one is cleaning up and "quenching" the alkali metal. Such procedures usually involve the use of flammable organic solvents, making such accidents quite severe. A proper Class D extinguisher should be available where alkali metals are utilized.
The lithium ion (Li+) is a psychoactive agent so avoid inhalation or ingestion of lithium-containing materials by using proper personal protective equipment such as dust masks, fume hoods, and gloves. See below for links concerning the use of lithium in treating manic depression (bipolar disorder).
Anyone working with alkali metals needs a Class D fire extinguisher. Get yours from Safety Emporium.
Disclaimer: The information contained herein is believed to be true and accurate, however ILPI makes no guarantees concerning the veracity of any statement. Use of any information on this page is at the reader's own risk. ILPI strongly encourages the reader to consult the appropriate local, state and federal agencies concerning the matters discussed herein.