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The term applies particularly to very fine solid particles as a suspension in air. This closely matches the definition of dust, the main difference being that fumes are airborne whereas dusts need not be suspended in the air.
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TiCl4 + 2 H2O TiO2(s) + 4 HCl(g)
The TiO2 (titania), is a solid that forms small white particles. The HCl (hydrogen chloride) is an invisible and hygroscopic gas that immediately condenses with water vapor in the air to form suspended liquid particles. The droplets in this HCl mist are acidic aqueous, solutions of hydrochloric acid.
Inhalation of these fumes is dangerous because each component is hazardous. The hydrochloric acid droplets can cause chemical burns to the respiratory system, eyes and skin; the fine particles of titania further irritate the damaged tissues.
Therefore, always try to control or eliminate the generation of fumes in the first place. Use appropriate ventilation such as fume hoods and other engineering controls. If the fumes are not adequately controlled with these methods, always use proper personal protective equipment (PPE) such as supplied air respirators.
Finally, note that many metal fumes, such as those generated in metal refining operations, soldering, and welding are significant health hazards. A general class of occupational disease is called metal fume fever. See the links below for more info.
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Entry last updated: Monday, August 22, 2016. This page is copyright 2000-2016 by ILPI. Unauthorized duplication or posting on other web sites is expressly prohibited. Send suggestions, comments, and new entry desires (include the URL if applicable) to us by email.
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